Phenolic glycosides from Kaempferia

Azuma, Toshiaki; Tanaka, Yasuo; Kikuzaki, Hiroe

https://doi.org/10.1016/j.phytochem.2008.09.001

Abstract

Three phenolic glycosides were isolated together with two known flavonol glycosides from the H2O-soluble fraction of rhizomes of Kaempferia parviflora. Their structures were determined to be rel-(5aS,10bS)-5a,10b-dihydro-1,3,5a,9-tetrahydroxy-8-methoxy-6H-benz[b]indeno[1,2-d]furan-6-one 5a-O-[a-l-rhamnopyranosyl-(1 ? 6)-ß-d-glucopyranoside] (1), its rel-5aS,10bR isomer (2), and (2R,3S,4S)-3-O-[a-l-rhamnopyranosyl-(1 ? 6)-ß-d-glucopyranosyl]-3'-O-methyl-ent-epicatechin-(2a ? O ? 3,4a ? 4)-(5aS,10bS)-5a,10b-dihydro-1,3,5a,9-tetrahydroxy-8-methoxy-6H-benz[b]indeno[1,2-d]furan-6-one 5a-O-[a-l-rhamnopyranosyl-(1 ? 6)-ß-d-glucopyranoside] (3). The structures were elucidated on the basis of analyses of chemical and spectroscopic evidence.

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